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SYNTHESIS AND PROPERTIES OF ALKYLNITROAMINO-1,2,4,5-TETRAZINES

Г. Ф. Рудаков, Т. В. Устинова, И. Б. Козлов, В. Ф. Жилин
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Abstract


Using a series of 1,2,4,5-tetrazine alkylamino derivatives the peculiarities of their reactivity under acidic nitration conditions were demonstrated. It was found that the degree of nitration of N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines is determined by nitric acid concentration and the alkyl substituent at the exocyclic nitrogen atom. A new method of the synthesis of unsymmetrically substituted N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines from N-alkyl-1,2,4,5-tetrazine-3-amine N-nitro derivatives was developed.

How to Cite
Rudakov, G. F.; Ustinova, T. V.; Kozlov, I. B.; Zhilin, V. F. Chem. Heterocycl. Compd. 2014, 50, 53. [Khim. Geterotsikl. Soedin. 2014, 59.]

For this article in the English edition see DOI 10.1007/s10593-014-1448-9


Keywords


1,2,4,5-tetrazines; nitration; nitramines; nucleophilic substitution

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