SYNTHESIS AND PROPERTIES OF ALKYLNITROAMINO-1,2,4,5-TETRAZINES

Authors

  • Г. Ф. Рудаков Российский Химико-Технологический Университет им. Д.И. Менделеева
  • Т. В. Устинова Российский Химико-Технологический Университет им. Д.И. Менделеева
  • И. Б. Козлов Российский Химико-Технологический Университет им. Д.И. Менделеева
  • В. Ф. Жилин Российский Химико-Технологический Университет им. Д.И. Менделеева

DOI:

https://doi.org/10.1007/1171

Keywords:

1, 2, 4, 5-tetrazines, nitration, nitramines, nucleophilic substitution

Abstract

Using a series of 1,2,4,5-tetrazine alkylamino derivatives the peculiarities of their reactivity under acidic nitration conditions were demonstrated. It was found that the degree of nitration of N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines is determined by nitric acid concentration and the alkyl substituent at the exocyclic nitrogen atom. A new method of the synthesis of unsymmetrically substituted N,N'-dialkyl-1,2,4,5-tetrazine-3,6-diamines from N-alkyl-1,2,4,5-tetrazine-3-amine N-nitro derivatives was developed.

How to Cite
Rudakov, G. F.; Ustinova, T. V.; Kozlov, I. B.; Zhilin, V. F. Chem. Heterocycl. Compd. 2014, 50, 53. [Khim. Geterotsikl. Soedin. 2014, 59.]

For this article in the English edition see DOI 10.1007/s10593-014-1448-9

Author Biography

Г. Ф. Рудаков, Российский Химико-Технологический Университет им. Д.И. Менделеева

Геннадий Федорович Рудаков

старший преподаватель кафеды "Химии и технологии органических соединений азота"

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Published

2014-01-20

Issue

No. 1 (2014)

Section

Original Papers