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NOVEL QUININE, LUPININE, AND ANABASINE DERIVATIVES CONTAINING DITHIOPHOSPHINATE GROUPS

А. В. Артемьев, С. Ф. Малышева, Н. К. Гусарова, Н. А. Белогорлова, С. В. Федоров, Б. В. Тимохин, В. И. Смирнов, Б. А. Трофимов
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Abstract


A three-component, atom-economic reaction between natural quinine, lupinine, or anabasine, secondary phosphines, and elemental sulfur occurs under mild conditions to yield previously unknown optically active dithiophosphinates.

Authors: A. V. Artem'ev, S. F. Malysheva, N. K. Gusarova, N. A. Belogorlova, S. V. Fedorov, B. V. Timokhin, V. I. Smirnov, and B. A. Trofimov.

English Translation in Chemistry of Heterocyclic Compounds, 2012, 48 (3), pp 448-452

http://link.springer.com/article/10.1007/s10593-012-1013-3


Keywords


anabasine; bis(2-arylethyl)phosphines; dithiophosphinates; elemental sulfur; lupinine; quinine; synthesis; three-component reaction

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