VINYLATION OF PYRIDYLCARBOXAMIDES WITH VINYLTRIMETHOXYSILANE

Authors

  • П. Арсенян Latvian Institute of Organic Synthesis
  • А. Петренко Latvian Institute of Organic Synthesis
  • С. Беляков Latvian Institute of Organic Synthesis

DOI:

https://doi.org/10.1007/1322

Keywords:

amide, copper(II) acetate, vinyl amide, vinyltrimethoxysilane, silane, catalysis, X-ray structural analysis

Abstract

A convenient method has been developed for the direct N-vinylation of pyridylcarboxamides with vinyltrimethoxysilane in the presence of copper(II) acetate and tetrabutylammonium fluoride. The yield of N-vinylamides depends on the nature of the starting amide and the solvent. The molecular structure of the products was confirmed by X-ray structural analysis.

Authors: P. Arsenyan, A. Petrenko, and S. Belyakov.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (12), pp 1527-1532

http://link.springer.com/article/10.1007/s10593-012-0943-0

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Published

2013-12-06

Issue

No. 12 (2011)

Section

Original Papers