SYNTHESIS AND CRYSTAL STRUCTURE OF A SOLVATE OF ARSENIC 4,6-DIMETHYL-8-QUINOLINETHIOLATE

Authors

  • Э. Силинь Institute of Inorganic Chemistry, Riga Technical University
  • С. Беляков Latvian Institute of Organic Synthesis
  • Я. Ашакс Institute of Inorganic Chemistry, Riga Technical University
  • Л. Печ Institute of Inorganic Chemistry, Riga Technical University
  • Д. Зарума Institute of Inorganic Chemistry, Riga Technical University

DOI:

https://doi.org/10.1007/1327

Keywords:

8-quinolinethiolates, intracomplex arsenic compounds, molecular and crystal structure

Abstract

A crystallosolvate of arsenic 4,6-dimethyl-8-quinolinethiolate, As[4,6-Me2C9H4NS]3·CHCl3 has been synthesized. The molecular and crystalline structures of the compound have been determined by X-ray structural analysis. The influence of the composition and structure of the ligand on the geometry of the coordination environment of the central arsenic atom in the investigated crystal structures of intracomplex compounds of 8-quinolinethiols is discussed.

Authors: E. Silina, S. Belyakov, J. Ashaks, L. Pech, and D. Zaruma.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (12), pp 1544-1550

http://link.springer.com/article/10.1007/s10593-012-0946-x

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Published

2013-12-09

Issue

No. 12 (2011)

Section

Original Papers