GERMYLENES DERIVED FROM PYRIDINE CONTAINING DIOLS: REACTIONS WITH DIPHENYLPHOSPHORYL AZIDE AND 9,10 PHENANTHRENEQUINONE

Authors

  • М. Хуан M. V. Lomonosov Moscow State University
  • М. М. Киреенко M. V. Lomonosov Moscow State University
  • К. В. Зайцев M. V. Lomonosov Moscow State University
  • Ю. Ф. Опруненко M. V. Lomonosov Moscow State University
  • А. В. Чураков N. S. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences
  • С. С. Карлов M. V. Lomonosov Moscow State University
  • Г. С. Зайцева M. V. Lomonosov Moscow State University

DOI:

https://doi.org/10.1007/1332

Keywords:

germylenes, hypervalent germanium, pyridine-containing diols, 1, 4-cycloaddition, oxidation, X ray structural analysis

Abstract

A study was carried out on the behavior of monomeric germylenes derived from pyridine-containing diols in reactions with diphenylphosphoryl azide and 9,10-phenanthrenequinone. It was found that the germanium atom increases its oxidation state to 4+ in these reactions. The structure of the product of the reaction with 9,10 phenanthrenequinone was confirmed by X-ray structural analysis, which showed a transannular germanium-nitrogen interaction in this product.

Authors: M. Huang, M. M. Kireenko, K. V. Zaitsev, Yu. F. Oprunenko, A. V. Churakov, S. S. Karlov, and G. S. Zaitseva.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (12), pp 1584-1589

http://link.springer.com/article/10.1007/s10593-012-0950-1

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Published

2013-12-09

Issue

No. 12 (2011)

Section

Original Papers