NOVEL ROUTE TO THE SYNTHESIS OF CHALCOGENOLANES, CHALCOGENANES, AND 1,2-DICHALCOGENAEPANES

Authors

  • Е. П. Леванова A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • В. А. Грабельных A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • А. Е. Елаев A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • Н. В. Руссавская A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • Л. В. Клыба A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • А. И. Албанов A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences
  • Н. А. Корчевин A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1343

Keywords:

1, 2-dichalcogenaepanes, chalcogenanes, chalcogenonium salts, chalcogenolanes, hydrazine hydrate–alkali systems

Abstract

The saturated heterocyclic compounds C4H8Y, C5H10Y, and C5H10Y2 (Y = Se or Te) have been prepared by the reaction of 1,4-dibromobutane or 1,5-dibromopentane with potassium chalcogenides. The novelty of the route consists of the use of the hydrazine hydrate–KOH system for the reductive generation of potassium selenide, telluride, diselenide or ditelluride from elemental chalcogens.

Authors: E. P. Levanova, V. A. Grabel'nykh, A. V. Elaev, N. V. Russavskaya, L. V. Klyba, A. I. Albanov, and N. A. Korchevin.

English translation in Chemistry of Heterocyclic Compounds, 2011, 47 (11), pp 1345-1352

http://link.springer.com/article/10.1007/s10593-012-0920-7

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Published

2013-12-11

Issue

No. 11 (2011)

Section

Original Papers