REACTION OF 3-ALKANOYLQUINOXALIN-2-ONES WITH AMMONIUM ACETATE IN DMSO – A NEW METHOD FOR THE SYNTHESIS OF PYRROLES

Authors

  • А. А. Калинин A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences
  • В. А. Мамедов A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1478

Keywords:

3-alkanoylquinoxalin-2-ones, 2, 5-di(quinoxalin-2-on-3-yl)pyrroles, macrocycle

Abstract

The interaction of 3-alkanoylquinoxalin-2-ones with NH4OAc in DMSO at 105-120°С produced pyrrole derivatives according to a novel [С2+N+С2] scheme, while the –(CO)–CH2– fragment of the substituent at position 3 of the quinoxalinones served as the source of two-carbon fragments С(2)–С(3) and С(4)–С(5), and the nitrogen source was NH4OAc.

How to Cite
Kalinin, A. A.; Mamedov, V. A. Chem. Heterocycl. Compd. 2014, 50, 195. [Khim. Geterotsikl. Soedin. 2014, 219.]

For this article in the English edition see DOI 10.1007/s10593-014-1461-z

Author Biographies

А. А. Калинин, A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences

Алексей Александрович Калинин

В. А. Мамедов, A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences

Вахид Абдулла-оглы Мамедов

заведующий лабораторией Химии гетеро­цик­лических соединений УРАН ИОФХ им. А.Е. Арбузова КазНЦ РАН д.х.н., профессор

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Published

2014-02-28

Issue

No. 2 (2014)

Section

Original Papers