INVESTIGATION OF THE SOLUTION PHASE CHEMILUMINESCENCE OF 1,2,4-TRIAZOLE DERIVATIVES

Authors

  • Р. Р. Каюмова Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences
  • Р. Р. Муслухов Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences
  • М. Ф. Абдуллин Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences
  • Е. Э. Клен Bashkir State Medical University
  • Ф. А. Халиуллин Bashkir State Medical University
  • Г. Ф. Магадеева Bashkir State Medical University
  • А. В. Мамыкин Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences
  • С. Л. Хурсан Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/1526

Keywords:

superoxide, 1, 2, 4-triazole derivatives, mass spectrometry, fluorescence, chemiluminescence

Abstract

We discovered and studied the chemiluminescence occurring during the oxidation of 3-bromo-5‑hydrazino-1-(thietan-3-yl)-1H-1,2,4-triazole with superoxide anion. The chemiluminescence wavelength interval was 400-590 nm with the maxima (at 436 and 540 nm) matching the peak fluorescence wavelengths of the reaction products. The possible reaction products were determined by NMR spectroscopy, mass spectrometry, IR and UV spectroscopy. The quantum yield of chemiluminescence was 10-9 E/mol.

How to Cite
Kayumova, R. R.; Muslukhov, R. R.; Abdullin, M. F.; Klen, E. E.; Khaliullin, F. A.; Magadeeva, G. F.; Mamykin, A. V.; Khursan, S. L. Chem. Heterocycl. Compd. 2014, 50, 979. [Khim. Geterotsikl. Soedin. 2014, 1062.]

For this article in the English edition see DOI 10.1007/s10593-014-1553-9

Author Biographies

Р. Р. Каюмова, Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

Каюмова Регина Робертовна

Младший научный сотрудник, лаборатория химической физики

Р. Р. Муслухов, Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

Муслухов Ринат Рафаисович

М. Ф. Абдуллин, Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

Абдуллин Марат Фаритович

Е. Э. Клен, Bashkir State Medical University

Клен Елена Эдмундовна

Ф. А. Халиуллин, Bashkir State Medical University

Халиуллин Феркат Адельзянович

Г. Ф. Магадеева, Bashkir State Medical University

Магадеева Гульназ Фатиховна

А. В. Мамыкин, Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

Мамыкин Александр Васильевич

С. Л. Хурсан, Institute of Organic Chemistry, Ural Scientific Center, Russian Academy of Sciences

Хурсан Сергей Леонидович

Downloads

Published

2014-08-08

Issue

No. 7 (2014)

Section

Original Papers