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THE INTERACTION OF 1H-AZOLES WITH NITROSOCHLORIDES OF ADAMANTANE SERIES

П. Е. Красников, Е. А. Сиднин, В. А. Осянин, Ю. Н. Климочкин
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Abstract


The interaction of nitrosochlorides based on 2-alkylidene adamantanes and 1Н‑azoles in pyridine medium produced α-azolyl oximes of adamantane series. The reaction occurred as a conjugated 1,4‑addition to in situ generated nitrosoalkenes acting as Michael acceptors. The structure of phenyl-[2-(4-phenyl-1Н‑imidazol-1-yl)adamantan-2-yl]methanone (Е)-oxime was studied by X-ray crystallography.

How to Cite
Krasnikov, P. E.; Sidnin, E. A.; Osyanin, V. A.; Klimochkin, Yu. N. Chem. Heterocycl. Compd. 2014, 50, 1090. [Khim. Geterotsikl. Soedin. 2014, 1183.]

For this article in the English edition see DOI 10.1007/s10593-014-1568-2


Keywords


alkylidene adamantanes; α-azolyl oximes; 1Н-azoles; nitrosoalkenes; nitrosochlorides; aza-Michael reaction

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