THE REACTION OF 3-ARYL-2-CYANOPROP-2-ENETHIOAMIDES WITH BROMONITROMETHANE: A NEW APPROACH TO FUNCTIONALIZED 1,2,4-THIADIAZOLES

Authors

  • В. В. Доценко ChemEx Lab
  • С. Г. Кривоколыско

DOI:

https://doi.org/10.1007/1706

Keywords:

bromonitromethane, 2-cyanoprop-2-enethioamides, cyanothioacetamide, dimethylsulfoxide, 1, 2, 4-thiadiazoles, oxidative dimerization

Abstract

The reaction of 3-aryl-2-cyanoprop-2-enethioamides with bromonitrometahne leads to the products of oxidative dimerization – (2Е,2'E)-2,2'-(1,2,4-thiadiazolе-3,5-diyl)bis(3-arylacrylonitriles). Their structure was confirmed by the counter synthesis through the oxidation of 3-aryl-2-cyanoprop-2-enethioamides by the DMSO–HCl system.

How to Cite
Dotsenko, V. V.; Krivokolysko, S. G. Chem. Heterocycl. Compd. 2014, 50, 557. [Khim. Geterotsikl. Soedin. 2014, 607.]

For this article in the English edition see DOI 10.1007/s10593-014-1507-2

Published

2014-05-08

Issue

Section

Original Papers