SYNTHESIS AND STRUCTURE OF A NEW POLYDENTATE 8-HYDROXYQUINOLINE LIGAND SYSTEM WITH A 1,3-TROPOLONE FRAGMENT AT POSITION 2 IN THE QUINOLINE RING
DOI:
https://doi.org/10.1007/1742Keywords:
1, 2-benzoquinone, 8-hydroxy-2-methylquinoline, 3-tropolone, intramolecular hydrogen bond, ring expansion reactionAbstract
An original three-step method has been developed for the synthesis of a new polydentate 8‑hydroxyquinoline ligand system with a 1,3-tropolone fragment at position 2 of the quinoline ring. X‑ray diffraction structural analysis, 1H and 13C NMR spectroscopy, and quantum-chemical calculations showed that this ligand exists in the NH-tautomeric form with the phenolic hydroxyl group in the exo position of the quinoline ring.
How to Cite
Mikhailov, I. E.; Kolodina, A. A.; Dushenko, G. A.; Artyushkina, Yu. M.; Tkachev, V. V.; Aldoshin, S. M.; Sayapin, Yu. A.; Minkin, V. I. Chem. Heterocycl. Compd. 2014, 50, 828. [Khim. Geterotsikl. Soedin. 2014, 897.]
For this article in the English edition see DOI 10.1007/s10593-014-1537-9
