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PHOSPHORYLATED BISTRIAZOLES: NEW ATROPOISOMERIC LIGANDS FOR CHIRAL CATALYSTS

А. А. Кирильчук, А. А. Юрченко, Ю. Г. Власенко, А. Н. Костюк, А. Б. Роженко
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Abstract


Promising atropochiral ligands – diphenylphosphino-derivatives of bis-triazoles – were synthesized via direct phosphorylation of starting bis-triazoles with diphenylchlorophosphine. Crystal structure of these substances was studied by single-crystal x-ray diffractional analysis. Conformations of these compounds were investigated at DFT level.

How to Cite
Kirilchuk, A. A.; Yurchenko, A. A.; Vlasenko, Yu. G.; Kostyuk, A. N.; Rozhenko, A. B. Chem. Heterocycl. Compd. 2015, 50, 1559. [Khim. Geterotsikl. Soedin. 2014, 1697.]

For this article in the English edition see DOI 10.1007/s10593-014-1624-y


Keywords


BINAP; atropochirality; phosphines; DFT; 1,2,4-triazole; XRDA



 

 

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