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GRINDING-INDUCED SYNTHESIS OF HETEROCYCLIC FULLERENE DERIVATIVES UNDER SOLVENT-FREE CONDITIONS

Javad Safaei-Ghomi, Reihaneh Masoomi
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Abstract


In this research, a green, easy, and effective solvent-free procedure for the synthesis of heterocyclic fullerene derivatives has been achieved via 1,3-dipolar cycloaddition reaction of C60, substituted arylhydrazones/oximes, and PhI(OAc)2 under grinding as a simple physical-mechanical method. This approach does not involve any hazardous organic solvent and has various advantages including design of safe reaction conditions moderate to good yields and short reaction times.

How to Cite
Safaei-Ghomi, J.; Masoomi, R. Chem. Heterocycl. Compd. 2015, 51, 39. [Khim. Geterotsikl. Soedin. 2015, 51, 39.]

For this article in the English edition see DOI 10.1007/s10593-015-1657-x


Keywords


fullerene; fulleroisoxazoline; fulleropyrazoline; cycloaddition reaction; grinding; solvent-free synthesis

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