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The mechanism of 5-amino-6-methyluracil oxidation with 1,4-dioxanyl peroxyl radical

Люция Р. Якупова, Ригина А. Насибуллина, Светлана Ф. Петрова, Марат Ф. Абдуллин, Шамиль М. Салихов, Альфия Р. Гимадиева, Рустам Л. Сафиуллин
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Abstract


The reaction of 1,4-dioxanyl peroxyl radical with 5-amino-6-methyluracil gave the following major products: 5,5,6-trihydroxy-6methyldihydropyrimidine-2,4(1H,3H)-dione, 6-hydroxy-6-methyldihydropyrimidine-2,4,5(3H)-trione, and 6-hydroxy-5-hydroxyimino-6-methyldihydropyrimidine-2,4(1H,3H)-dione. A radical chain reaction mechanism was proposed for the oxidation of 1,4-dioxane in the presence of 5-amino-6-methyluracil.

How to Cite
Yakupova, L. R.; Nasibullina, R. A.; Petrova, S. F.; Abdullin, M. F.; Salikhov, S. M.; Gimadieva, A. R.; Safiullin, R. L. Chem. Heterocycl. Compd. 2015, 51, 162. [Khim. Geterotsikl. Soedin. 2015, 51, 162.]

For this article in the English edition see DOI 10.1007/s10593-015-1675-8

 


Keywords


5-amino-6-methyluracil; 1,4-dioxane; oxidation products; peroxyl radical

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