NOVEL STRUCTURAL ANALOGS OF GLYPHOSATE BASED ON AZOLES. 1. SYNTHESIS OF 1<i>H</i>-IMIDAZOLES CONTAINING CARBOXYL AND PHOSPHORYL GROUPS IN THE RING

Authors

  • Н. В. Павленко Organic Chemistry Institute, Ukraine National Academy of Sciences
  • Т. И. Ус Organic Chemistry Institute, Ukraine National Academy of Sciences
  • Ю. Л. Ягупольский Organic Chemistry Institute, Ukraine National Academy of Sciences
  • А. ван Алмсик Bayer CropScience GmbH, Chemistry Frankfurt
  • Л. Виллмс Bayer CropScience GmbH, Chemistry Frankfurt

DOI:

https://doi.org/10.1007/2173

Keywords:

imidazole, lithium intermediates, electrophiles, hydrolysis, protecting groups, phosphorylation

Abstract

A general method has been developed for the synthesis of 1H-imidazoles containing a phosphoryl group in positions 2 or 4(5) based on lithium intermediates. The possibility of further functionalization of the ring using electrophiles has also been demonstrated.

How to Cite
Pavlenko, N. V.; Oos, T. I.; Yagupolskii, Yu. L.; van Almsick, A.; Willms, L. Chem. Heterocycl. Compd. 2011, 47(1), 36. [Khim. Geterotsikl. Soedin. 2011, 52.]

For this article in the English edition see DOI 10.1007/s10593-011-0717-0

Downloads

Published

2014-12-18

Issue

No. 1 (2011)

Section

Original Papers