SYNTHESIS OF 2-ARYL-4,5-BIS(POLYFLUOROALKYL)IMIDAZOLES FROM POLYFLUOROALKANETHIOCARBOXYLIC ACID AMIDES

Authors

  • Сергей С. Михайличенко Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • Надежда В. Пикун Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • Эдуард Б. Русанов Institute of Organic Chemistry, National Academy of Sciences of Ukraine
  • Юрий Г. Шермолович Institute of Organic Chemistry, National Academy of Sciences of Ukraine

DOI:

https://doi.org/10.1007/2194

Keywords:

aromatic aldehydes, 4, 5-bis(polyfluoroalkyl)imidazoles, bis(N-thioacyl)aminals, polyfluoroalkanethiocarboxylic acid amides, acylation

Abstract

Polyfluoroalkanethiocarboxylic acid amides react with aromatic aldehydes with the formation of bis(N-thioacyl)aminals. Treating the latter with acyl chlorides gives 2-aryl-substituted 4,5-bis(polyfluoroalkyl)imidazoles which constitutes a novel method of synthesizing these imidazole derivatives.

How to Cite
Mikhaylychenko, S. S.; Pikun, N. V.; Rusanov, E. B.; Shermolovich, Y. G. Chem. Heterocycl. Compd. 2015, 51, 128. [Khim. Geterotsikl. Soedin. 2015, 51, 128.]

For this article in the English edition see DOI 10.1007/s10593-015-1669-6

Author Biographies

Сергей С. Михайличенко, Institute of Organic Chemistry, National Academy of Sciences of Ukraine

Сергей Сергеевич Михайличенко

Надежда В. Пикун, Institute of Organic Chemistry, National Academy of Sciences of Ukraine

Надежда Викторовнa Пикун

Эдуард Б. Русанов, Institute of Organic Chemistry, National Academy of Sciences of Ukraine

Эдуард Борисович Русанов

Юрий Г. Шермолович, Institute of Organic Chemistry, National Academy of Sciences of Ukraine

Юрий Григорьевич Шермолович

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Published

2015-03-02

Issue

Vol. 51 No. 2 (2015)

Section

Original Papers