REARRANGEMENT OF OXAZOLO[3,2-<i>a</i>]PYRIDINES AS AN APPROACH OF SYNTHESIZING AZA[3.3.2]CYCLAZINES

Authors

  • Евгений В. Бабаев Lomonosov Moscow State University 1, Build. 3 Leninskie Gory, Moscow 119991, Russia
  • Александра А. Невская Lomonosov Moscow State University 1, Build. 3 Leninskie Gory, Moscow 119991, Russia
  • Илья В. Длинных Lomonosov Moscow State University 1, Build. 3 Leninskie Gory, Moscow 119991, Russia

DOI:

https://doi.org/10.1007/2222

Keywords:

5-aminoindolizines, oxazolo[3, 2-a]pyridines, pyrimido[6, 1, 2-cd]indolizines, cyclization, NMR spectroscopy, rearrangement

Abstract

5-methyloxazolo[3,2-a]pyridinium salts were shown to react with (methylamino)acetaldehyde dimethyl acetal leading to the formation of functionalized 5-aminoindolizines, which in turn are capable of closing the pyrimidine ring in acidic media forming aza[3.3.2]cyclazines.

How to Cite
Babaev, E. V.; Nevskaya, A. A.; Dlynnikh, I. V.Chem. Heterocycl. Compd. 2015, 51, 269. [Khim. Geterotsikl. Soedin. 2015, 51, 269.]

For this article in the English edition see DOI 10.1007/s10593-015-1685-6

Author Biography

Евгений В. Бабаев, Lomonosov Moscow State University 1, Build. 3 Leninskie Gory, Moscow 119991, Russia

Евгений Вениаминович Бабаев

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Published

2015-03-18

Issue

Vol. 51 No. 3 (2015)

Section

Original Papers