Open Access Open Access  Restricted Access Subscription Access

ALKYLATION OF IMIDAZOLE AND BENZIMIDAZOLE DERIVATIVES WITH 1-(IODOMETHYL)-1,1,3,3,3-PENTAMETHYLDISILOXANE – A NEW METHOD FOR THE PREPARATION OF ORGANOCYCLOSILOXANE IODIDES

Лариса В. Жилицкая, Нина О. Ярош, Людмила Г. Шагун, Иван А. Дорофеев, Людмила И. Ларина
Cover Image

Abstract


The reaction of imidazole and benzimidazole derivatives with 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane resulted in N1,3-alkylation, cleavage of siloxane bonds by the evolved hydrogen iodide, and the formation of cyclic organosilicon iodides and triiodides.

How to Cite
Zhilitskaya, L. V.; Yarosh, N. O.; Shagun, L. G.; Dorofeev, I. A.; Larina, L. I. Chem. Heterocycl. Compd. 2015, 51, 381. [Khim. Geterotsikl. Soedin. 2015, 51, 381.]

For this article in the English edition see DOI 10.1007/s10593-015-1711-8

 

 


Keywords


2-aminobenzimidazole; benzimidazole; imidazole; 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane; 2-methylimidazole; organocyclosiloxanes; alkylation

Full Text: PDF (Russian) Supplementary File(s): None


 

 

Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv