ALKYLATION OF IMIDAZOLE AND BENZIMIDAZOLE DERIVATIVES WITH 1-(IODOMETHYL)-1,1,3,3,3-PENTAMETHYLDISILOXANE – A NEW METHOD FOR THE PREPARATION OF ORGANOCYCLOSILOXANE IODIDES

Authors

  • Лариса В. Жилицкая A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Нина О. Ярош A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Людмила Г. Шагун A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Иван А. Дорофеев A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences
  • Людмила И. Ларина A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences

DOI:

https://doi.org/10.1007/2302

Keywords:

2-aminobenzimidazole, benzimidazole, imidazole, 1-(iodomethyl)-1, 1, 3, 3-pentamethyldisiloxane, 2-methylimidazole, organocyclosiloxanes, alkylation

Abstract

The reaction of imidazole and benzimidazole derivatives with 1-(iodomethyl)-1,1,3,3,3-pentamethyldisiloxane resulted in N1,3-alkylation, cleavage of siloxane bonds by the evolved hydrogen iodide, and the formation of cyclic organosilicon iodides and triiodides.

How to Cite
Zhilitskaya, L. V.; Yarosh, N. O.; Shagun, L. G.; Dorofeev, I. A.; Larina, L. I. Chem. Heterocycl. Compd. 2015, 51, 381. [Khim. Geterotsikl. Soedin. 2015, 51, 381.]

For this article in the English edition see DOI 10.1007/s10593-015-1711-8

 

 

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Published

2015-04-27

Issue

Vol. 51 No. 4 (2015)

Section

Original Papers