DIRECTED SYNTHESIS OF NEW SPIRO-FUSED PHOTOCHROMES OF DIARYLETHENE SERIES
DOI:
https://doi.org/10.1007/2446Keywords:
1, 2-diarylethanones, diarylethenes, tetracyanoethylene, ethene linker, non-bonded strain, photochromes, spiro compounds, spirofusion, tetracyanoethylationAbstract
The reaction of tetracyanoethylated 1,2-diarylethanones with morpholine was used for directed synthesis of spiro-fused diarylethenes, 8amino-1-imino(oxo)-6-morpholino-2-oxa-7-azaspiro[4.4]nona-3,6,8-triene-9-carbonitriles. The intermediates in this process were tetracyanoalkanone salts. The formation of spiranes was sensitive to the nature of aromatic substituents at the carbonyl group of 3,4diaryl-4-oxobutane-1,1,2,2-tetracarbonitriles. The obtained spiro-fused diarylethenes exhibited photochromic properties.
How to Cite
Belikov, M. Yu.; Ievlev, M. Yu.; Belikova, I. V.; Ershov, O. V.; Tafeenko, V. A.; Surazhskaya, M. D. Chem. Heterocycl. Compd. 2015, 51, 518. [Khim. Geterotsikl. Soedin. 2015, 51, 518.]
For this article in the English edition see DOI 10.1007/s10593-015-1731-4
