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Synthesis of γ-sultones based on conversion of adamantane-type olefins

Марат Р. Баймуратов, Марина В. Леонова, Виктор Б. Рыбаков, Юрий Н. Климочкин
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Abstract


γ-Sultones condensed with the homoadamantane polycycle were synthesized by sulfonation of 1-(adamant-1-yl)-substituted olefins. The formation of γ-sultones containing a substituent at the α-position to the sulfonyl group occurs stereospecifically: 1Н and 13С NMR data support the formation of only the threo diastereomer.

How to Cite
Baimuratov, M. R.; Leonova, M. V.; Rybakov, V. B.; Klimochkin, Yu. N. Chem. Heterocycl. Compd. 2015, 51, 582. [Khim. Geterotsikl. Soedin. 2015, 51, 582.]

For this article in the English edition see DOI 10.1007/s10593-015-1740-3

 


Keywords


adamantane; allyl bromides; homoadamantane; sultones; cage compounds; unsaturated compounds

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