THERMAL REARRANGEMENT OF CONDENSED ALKOXY-SUBSTITUTED 2-TRIFLUOROMETHYL-4H-PYRAN-4-ONES TO SPIROANNELATED 3(2H)-FURANONES

Authors

  • Д. Н. Бобров Belarus State University
  • А. С. Ляхов Belarus State University
  • А. А. Говорова Belarus State University
  • В. И. Тыворский Belarus State University

DOI:

https://doi.org/10.1007/281

Keywords:

acyloxy group, 2, 3-dihydro-4H-pyran-4-ones, spiro compounds, 3(2H)-furanones, X-ray crystallographic analysis, thermal rearrangement

Abstract

Isomerization of the acetates and benzoates of condensed hydroxy-substituted 2-trifluoromethyl-4H-pyran-4-ones at 300-320 ºC gave the corresponding derivatives of spiroannelated 3(2H)-furanones. Their structure was confirmed by spectral data and by X-ray crystallographic analysis.

Authors: D. N. Bobrov, A. S. Lyakhov, A. A. Govorova, and V. I. Tyvorskii.

English Translation in Chemistry of Heterocyclic Compounds, 2000, 36 (8), pp 899-904

http://link.springer.com/article/10.1007/BF02256973

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Published

2013-02-07

Issue

No. 8 (2000)

Section

Original Papers