FUNCTIONALIZED 2'-CARBOXAMIDODEOXYBENZOINS BY RING OPENING OF 3-ARYL-1<i>H</i>-ISOCHROMEN-1-ONES WITH SECONDARY AMINES

Authors

  • Olga V. Shablykina Kyiv National Taras Shevchenko University
  • Viktoriia S. Moskvina Kyiv National Taras Shevchenko University
  • Valentina V. Ishchenko Kyiv National Taras Shevchenko University
  • Eugeniia B. Valter Kyiv National Taras Shevchenko University
  • Volodymir P. Khilya Kyiv National Taras Shevchenko University

DOI:

https://doi.org/10.1007/3028

Keywords:

3-arylisocoumarins, 2'-carboxamidodeoxybenzoins, N-nucleophiles, amidation, ring opening

Abstract

An efficient approach based on pyrone ring opening in 3-arylisocoumarins in the presence of cyclic secondary amines was developed in order to prepare amides of deoxybenzoin-2'-carboxylic acids, diverse functionalized structures useful for the synthesis of polyfunctional compounds.

 

Author Biographies

Olga V. Shablykina, Kyiv National Taras Shevchenko University

Chemistry Department

Viktoriia S. Moskvina, Kyiv National Taras Shevchenko University

Chemistry Department

Valentina V. Ishchenko, Kyiv National Taras Shevchenko University

Chemistry Department

Eugeniia B. Valter, Kyiv National Taras Shevchenko University

Chemistry Department

Volodymir P. Khilya, Kyiv National Taras Shevchenko University

Chemistry Department

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Published

2016-04-11

Issue

Vol. 52 No. 4 (2016)

Section

Letters to the Editor