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SYNTHESIS OF NOVEL POLYCYCLIC HETEROSYSTEMS FROM 5-NITRO[1,2,5]SELENADIAZOLO[3,4-e]BENZOFUROXANS

Максим A. Бастраков, Алексей M. Старосотников, Александр A. Павлов, Игорь Л. Далингер, Святослав А. Шевелев
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Abstract


A method for the preparation of 5-nitro[1,2,5]selenadiazolo[3,4-e]benzofuroxan has been developed. Employing the reactivity of this compound in pericyclic (4+2) and (3+2) cycloaddition reactions as a dienophile or dipolarophile (at the C=C–NO2 bond) with a heterodiene (fragment C=C–N(O)=O) representatives of novel types of fused polycyclic heterosystems were synthesized.

Authors: Maxim A. Bastrakov*, Alexey M. Starosotnikov, Alexander A. Pavlov, Igor L. Dalinger, Svyatoslav A. Shevelev


Keywords


benzofuroxans; nitroarenes; selenadiazoles; nitrogen-oxygen systems; nitric oxide donors; Diels–Alder reaction

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