CYCLOADDITION OF FLUORINATED OXADIAZOLES WITH TRIALLYLAMINE

Authors

  • Nikolai V. Vasil'ev Moscow State Regional University, 10 Radio St., Moscow 107005
  • Georgy V. Zatonsky State Scientific Research Institute of Biological Engineering, 75–1 Volokolamskoe Shosse, Moscow 123424
  • Tatiana S. Kostryukova State Scientific Research Institute of Biological Engineering, 75–1 Volokolamskoe Shosse, Moscow 123424
  • Sergey Z. Vatsadze Moscow M. V. Lomonosov State University, 1 Leninskie Gory, Moscow 119991

DOI:

https://doi.org/10.1007/3341

Keywords:

fluorinated 1, 3, 4-oxadiazoles, triallylamine, (3 2) cycloaddition, (4 2) cycloaddition

Abstract

Cycloaddition reactions of 2,5-bis(trifluoromethyl)-1,3,4-oxadiazole and ethyl 5-(trifluoromethyl)-1,3,4-oxadiazole-2-carboxylate withtriallylamine were studied. The investigated reactions yielded products of further intramolecular cycloaddition – cage compounds of octahydro-2,7-methanofuro[3,2-c]pyridine series. The synthesized compounds had strongly basic properties and formed stable salts.

Author Biography

Nikolai V. Vasil'ev, Moscow State Regional University, 10 Radio St., Moscow 107005

Завкафедрой теоретической и прикладной химии

Downloads

Published

2016-10-25

Issue

Vol. 52 No. 9 (2016): Pericyclic reactions in heterocyclic chemistry

Section

Original Papers