SYNTHESIS AND (3+2)-CYCLOADDITION REACTIONS OF <i>N</i>,<i>N</i>ꞌ- AND <i>C</i>,<i>N</i>-CYCLIC AZOMETHINE IMINES

Authors

  • Наталия П. Бельская Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Yekaterinburg 620002
  • Василий А. Бакулев Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Yekaterinburg 620002
  • Джи Фан State Key Laboratory of Organoelement Chemistry, Nankai University, 94 Weijin Rd., Tianjin 300071, P. R. China; е-mail: fanzj@nankai.edu.cn Joint Innovation Center of Chemical Science and Engineering, Tianjin 300071, P. R. China

DOI:

https://doi.org/10.1007/3345

Keywords:

C, N-cyclic azomethine imines, N, N′-cyclic azomethine imines, pyrazolo[5, 1-a]isoquinolines, pyrazolo[1, 2-a]pyrazoles, (3 2)-cycloaddition

Abstract

This review considers new methods for the synthesis of N,Nꞌ- and C,N-cyclic azomethine imines, as well as the most characteristic of their transformations – (3+2)-dipolar cycloaddition reactions. Particular attention was focused on the issues of regio- and stereoselectivity, the effects of the structure of starting materials, solvents, and catalysts on the reaction direction and yields of cycloadducts. The review covers literature data about the chemistry of cyclic azomethine imines published over the previous 10 years. There are 71 references given.

Authors: N. P. Bel’skaya*, V. A. Bakulev, Z.-J. Fan

 

Author Biographies

Наталия П. Бельская, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Yekaterinburg 620002

профессор кафедры технологии органического синтеза

Василий А. Бакулев, Ural Federal University named after the first President of Russia B. N. Yeltsin, ul. Mira 19, Yekaterinburg 620002

профессор, заведующий кафедрой технологии органического синтеза

Джи Фан, State Key Laboratory of Organoelement Chemistry, Nankai University, 94 Weijin Rd., Tianjin 300071, P. R. China; е-mail: fanzj@nankai.edu.cn Joint Innovation Center of Chemical Science and Engineering, Tianjin 300071, P. R. China

профессор Государственной лаборатории элементо-органической химии, Нанькайский университет

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Published

2016-10-03

Issue

Vol. 52 No. 9 (2016): Pericyclic reactions in heterocyclic chemistry

Section

Review Articles