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SYNTHESIS OF MONOSUBSTITUTED 1,2,4,5-TETRAZINES – 3-AMINO-1,2,4,5-TETRAZINES

Геннадий Ф. Рудаков, Юрий А. Моисеенко, Наталия А. Спесивцева
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Abstract


The substitution of pyrazolyl moiety in 3-(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine with N-nucleophiles provided a series of high-nitrogen tetrazine derivatives, including 2-nitro-1-(1,2,4,5-tetrazin-3-yl)guanidine, N-(1H-tetrazol-5-yl)-1,2,4,5-tetrazin-3-amine, N-(1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazin-3-amine, N,N'-di(1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazine-3,6-diamine, N-(1,2,4,5-tetrazin-3-yl)[1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-amine, and tritetrazinylamine. The thermal stability of these new compounds was evaluated by differential scanning calorimetry and their energetic characteristics were calculated.

Authors: Gennady F. Rudakov*, Yurii A. Moiseenko, Natal'ya А. Spesivtseva


Keywords


ditetrazinylamines; N,N-di(1,2,4,5-tetrazin-3-yl)-1,2,4,5-tetrazin-3-amine; nitroguanidine; 1,2,4,5-tetrazine; 1H-tetrazol-5-amine; 1H-1,2,4-triazol-5-amine; nucleophilic substitution

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