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NITROGEN HETEROCYCLIC SALTS OF POLYHEDRAL BORANE ANIONS: FROM IONIC LIQUIDS TO ENERGETIC MATERIALS

Игорь Б. Сиваев
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Abstract


Synthesis, structure, and physical properties of nitrogen heterocyclic salts of the polyhedral borane anions (closo-decaborate [B10H10]2–, closo-dodecaborate [B12H12]2–, carba-closo-dodecaborate [CB11H12], and 3,3'-cobaltabis(1,2-dicarbollide) [3,3'-Co(1,2-C2B9H11)2])  and their derivatives, including their potential application as ionic liquids and energetic materials, are reviewed.

Author: Igor B. Sivaev


Keywords


carba-closo-dodecaborate anion; closo-decaborate anion; closo-dodecaborate anion; cobalt bis(dicarbollide); nitrogen heterocyclic cations; polyhedral boron hydrides; energetic materials; ionic liquids

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