A SIMPLE METHOD FOR THE PREPARATION OF 3,5-DINITRIMINO-1,2,4-TRIAZOLE AND ITS SALTS

Authors

  • Александр М. Астахов Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037
  • Денис В. Антишин Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037
  • Виталий А. Ревенко Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037
  • Александр Д. Васильев Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Build. 38, Krasnoyarsk 660036 Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk 660041
  • Эдуард С. Бука Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037

DOI:

https://doi.org/10.1007/3784

Keywords:

3, 5-dinitramino-1, 2, 4-triazole, 5-dinitrimino-1, 1, 4-triazoles, energetic compounds, nitramines, nitrimines, nucleophilic substitution

Abstract

The reaction of 2-methyl-1-nitrоisothiourea with hydrazine in the presence of alkali metal bicarbonates (carbonates) resulted in the formation of 3,5-dinitrimino-1,2,4-triazole salts. The same salts were also formed by a reaction of 2-methyl-1-nitrоisothiourea with alkali metal salts of 4-nitrоsemicarbazide. This represents the first synthesis and characterization of the high-energy 3,5-dinitrimino-1,2,4-triazole, which can be readily isolated by treatment of its disodium salt with HCl.

Authors: Alexander M. Astakhov*, Denis V. Antishin, Vitalii A. Revenko, Alexander D. Vasiliev, Eduard S. Buka

Author Biographies

Александр М. Астахов, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037

доцент кафедры ХТОСА

Денис В. Антишин, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037

аспирант кафедры ХТОСА

Виталий А. Ревенко, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037

научный сотрудник

Александр Д. Васильев, Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Build. 38, Krasnoyarsk 660036 Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk 660041

С.н.с. института физики, доцент СФУ

Эдуард С. Бука, Reshetnev Siberian State University of Science and Technology, 31 Krasnoyarsky Rabochy Ave., Krasnoyarsk 660037

зав.кафедрой ХТОСА

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Published

2017-08-18

Issue

Vol. 53 No. 6/7 (2017): Heterocycle-based energetic materials

Section

Original Papers