SYNTHESIS OF 5-AZIDO-3-NITRO-1<i>H</i>-1,2,4-TRIAZOLE BY USING A CYANOETHYL ACTIVATING GROUP

Authors

  • Владимир В. Толстяков Saint Petersburg State Institute of Technology (Technical University), 26 Moskovsky Ave., Saint Petersburg 190013

DOI:

https://doi.org/10.1007/3818

Keywords:

azidotriazole, nitrotriazole, azidation, nucleophilic substitution, cyanoethylation

Abstract

A new method is proposed for the preparation of 5-azido-3-nitro-1H-1,2,4-triazole, based on cyanoethylation of 5-bromo-3-nitro-1H-1,2,4-triazole, nucleophilic substitution of bromide with azide ion, and removal of cyanoethyl protecting group.

Author: Vladimir V. Tolstyakov

Author Biography

Владимир В. Толстяков, Saint Petersburg State Institute of Technology (Technical University), 26 Moskovsky Ave., Saint Petersburg 190013

St. Petersburg State Institute of Technology (Technical University), research engineer

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Published

2017-08-18

Issue

Vol. 53 No. 6/7 (2017): Heterocycle-based energetic materials

Section

Original Papers