A UNIQUE EXAMPLE OF NONCATALYZED [3+2] CYCLOADDITION INVOLVING (2<i>E</i>)-3-ARYL-2-NITROPROP-2-ENENITRILES

Authors

  • Magdalena Żmigrodzka Cracow University of Technology, Institute of Organic Chemistry and Technology, 24 Warszawska, Cracow 31-155
  • Ewa Dresler Institute of Heavy Organic Synthesis ''Blachownia'', 9 Energetyków, Kędzierzyn-Koźle 47-225
  • Zofia Hordyjewicz-Baran Institute of Heavy Organic Synthesis ''Blachownia'', 9 Energetyków, Kędzierzyn-Koźle 47-225
  • Renata Kulesza Institute of Heavy Organic Synthesis ''Blachownia'', 9 Energetyków, Kędzierzyn-Koźle 47-225
  • Radomir Jasiński Cracow University of Technology, Institute of Organic Chemistry and Technology, 24 Warszawska, Cracow 31-155

DOI:

https://doi.org/10.1007/3955

Keywords:

nitroalkene, ylide, [3 2] cycloaddition, molecular electron density theory

Abstract

N-Methylazomethine ylide reacts in boiling benzene with (2E)-3-aryl-2-nitroprop-2-enenitriles via [3+2] cycloaddition scheme. This is an evidently rare case of [3+2] cycloaddition of this group of conjugated nitroalkenes

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Published

2017-11-29

Issue

Vol. 53 No. 10 (2017)

Section

Short Communications