SYNTHESIS OF  N -SUBSTITUTED TETRAPROPARGYLAMINES BY CATALYTIC AMINOMETHYLATION OF Α,Ω-DIACETYLENES

Гузель Р. Хабибуллина; Фируза Т. Зайнуллина; Татьяна В. Тюмкина; Марат Ф. Абдуллин; Асхат Г. Ибрагимов

doi:10.1007/4807

SYNTHESIS OF N-SUBSTITUTED TETRAPROPARGYLAMINES BY CATALYTIC AMINOMETHYLATION OF Α,Ω-DIACETYLENES

Гузель Р. Хабибуллина, Фируза Т. Зайнуллина, Татьяна В. Тюмкина, Марат Ф. Абдуллин, Асхат Г. Ибрагимов

Abstract

A catalytic method was developed for the synthesis of N-substituted tetrapropargylamines by reactions of α,ω-diacetylenes with 1,5,3-dioxazepanes, aldehydes (benzaldehydes, formaldehyde), and cyclic secondary amines.

Keywords

copper(I) chloride, α,ω-diacetylenes, 1,5,3-dioxazepanes, tetrapropargylamines, aminomethylation.

Full Text: PDF (Russian) Open Access

Supplementary File(s): None

Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv

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