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SYNTHESIS OF 4-POLYFLUOROALKYL-1,3-DITHIOLANES via [3+2] CYCLOADDITION OF THIOCARBONYL YLIDE TO POLYFLUOROALKANETHIOAMIDES

Сергей С. Михайличенко, Юрий Н. Маркитанов, Тимофей В. Руденко, Эдуард Б. Русанов, Юрий Г. Шермолович
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Abstract


New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.

Authors: Sergiy S. Mykhaylychenko*, Yuriy N. Markitanov, Timofii V. Rudenko, Eduard B. Rusanov, Yuriy G. Shermolovich


Keywords


1,3-dithiolane; polyfluoroalkanethiocarboxylic acids; thioamide; thiocarbonyl ylide; [3+2] cycloaddition

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