SYNTHESIS OF 4-POLYFLUOROALKYL-1,3-DITHIOLANES <i>via</i> [3+2] CYCLOADDITION OF THIOCARBONYL YLIDE TO POLYFLUOROALKANETHIOAMIDES

Authors

  • Сергей С. Михайличенко Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660
  • Юрий Н. Маркитанов Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660
  • Тимофей В. Руденко Enamine Ltd., 78 Krasnotkatska St., Kyiv 02094
  • Эдуард Б. Русанов Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660
  • Юрий Г. Шермолович Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660

DOI:

https://doi.org/10.1007/4884

Keywords:

1, 3-dithiolane, polyfluoroalkanethiocarboxylic acids, thioamide, thiocarbonyl ylide, [3 2] cycloaddition

Abstract

New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.

Authors: Sergiy S. Mykhaylychenko*, Yuriy N. Markitanov, Timofii V. Rudenko, Eduard B. Rusanov, Yuriy G. Shermolovich

Author Biographies

Сергей С. Михайличенко, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660

отдел химии органических соединений серы, старший научный сотрудник

Юрий Н. Маркитанов, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660

отдел химии органических соединений серы, научный сотрудник

Эдуард Б. Русанов, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660

отдел физико-химических исследований, старший научный сотрудник

Юрий Г. Шермолович, Institute of Organic Chemistry, National Academy of Sciences of Ukraine, 5 Murmanska St., Kyiv 02660

заведующий отделом химии органических соединений серы, профессор

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Published

2019-03-11

Issue

Vol. 55 No. 2 (2019)

Section

Short Communications