SYNTHESIS OF 4-POLYFLUOROALKYL-1,3-DITHIOLANES  via  [3+2] CYCLOADDITION OF THIOCARBONYL YLIDE TO POLYFLUOROALKANETHIOAMIDES

Сергей С. Михайличенко; Юрий Н. Маркитанов; Тимофей В. Руденко; Эдуард Б. Русанов; Юрий Г. Шермолович

doi:10.1007/4884

SYNTHESIS OF 4-POLYFLUOROALKYL-1,3-DITHIOLANES via [3+2] CYCLOADDITION OF THIOCARBONYL YLIDE TO POLYFLUOROALKANETHIOAMIDES

Сергей С. Михайличенко, Юрий Н. Маркитанов, Тимофей В. Руденко, Эдуард Б. Русанов, Юрий Г. Шермолович

Abstract

New 4-polyfluoroalkyl-1,3-dithiolanes were synthesized by reaction of polyfluoroalkanethioamides with thiocarbonyl ylide that was generated in situ by desilylation of chloromethyl (trimethylsilyl)methyl sulfide with tetramethylammonium fluoride.

Authors: Sergiy S. Mykhaylychenko*, Yuriy N. Markitanov, Timofii V. Rudenko, Eduard B. Rusanov, Yuriy G. Shermolovich

Keywords

1,3-dithiolane; polyfluoroalkanethiocarboxylic acids; thioamide; thiocarbonyl ylide; [3+2] cycloaddition

Full Text: PDF (Russian) Open Access

Supplementary File(s): None

Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv

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