CATALYTIC REACTION OF SUBSTITUTED 1,3-OXATHIOLANES WITH DIAZOCARBONYL COMPOUNDS
Authors
Гульнур Н. Сахабутдинова
Ufa State Petroleum Technological University,
1 Kosmonavtov St., Ufa 450062, Russia
Гульнара З. Раскильдина
Ufa State Petroleum Technological University,
1 Kosmonavtov St., Ufa 450062, Russia
Ирина П. Байкова
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences,
71 Oktyabrya Ave., Ufa 450054, Russia
Семен С. Злотский
Ufa State Petroleum Technological University,
1 Kosmonavtov St., Ufa 450062, Russia
Римма М. Султанова
Ufa State Petroleum Technological University,
1 Kosmonavtov St., Ufa 450062, Russia
Ufa Institute of Chemistry, Ufa Federal Research Center of the Russian Academy of Sciences,
71 Oktyabrya Ave., Ufa 450054, Russia
diazoesters, ylides, 1, 3-oxathiolanes, thietanes, homogeneous catalysis, insertion into the C–S bond, intramolecular rearrangements.
Abstract
The reaction of substituted 1,3-oxathiolanes with diazocarbonyl compounds in the presence of Cu(OTf)2 and Rh2(OAc)4 was studied. The reaction is accompanied by the insertion of an alkoxycarbonylmethylene fragment into the C–S bond of the oxathiolane ring and leads to the formation of heterocyclic and heteroaliphatic products.
Author Biography
Гульнара З. Раскильдина, Ufa State Petroleum Technological University,
1 Kosmonavtov St., Ufa 450062, Russia
