EFFECTIVE BIMETALLIC COMPOSITE CATALYSTS FOR THE SYNTHESIS OF ARYLATED FURANS AND THIOPHENES IN AQUEOUS MEDIA

Authors

  • Николай А. Бумагин Московский государственный университет им. М. В. Ломоносова
  • Сергей К. Петкевич
  • Алексей В. Клецков
  • Роман С. Алексеев
  • Владимир И. Поткин

DOI:

https://doi.org/10.1007/5058

Keywords:

cobalt, furan, isoxazole, nickel, palladium, pyrimidine, thiophene, bimetallic catalyst, heterogeneous catalysis, Suzuki reaction

Abstract

N-(4,6-Dimethylpyrimidin-2-yl)-5-phenylisoxazole-3-carboxamide was used as a ligand for obtaining bimetallic boron-containing heterogeneous catalysts Pd–Ni(Co)–B–L (Ni(Co):Pd = 9:1). The obtained composites were highly active as catalysts of Suzuki reaction in aqueous media, allowing to develop convenient methods for the synthesis of heterobiaryls containing furyl and thienyl rings.

Author Biography

Николай А. Бумагин, Московский государственный университет им. М. В. Ломоносова

Ведущий научный сотрудник кафедры органической химии, доктор химических наук, профессор

Published

2019-07-23