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NUCLEOPHILIC ADDITION OF AMIDE ANIONS TO 1-METHYL-5(6,7,8)-NITROQUINOLINIUM SALTS

Елена К. Авакян, Гульминат А. Амангазиева, Олег П. Демидов, Анастасия А. Боровлева, Елена С. Бекетова, Оксана А. Нечаева, Иван В. Боровлев
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Abstract


The stable adducts, N-(1-methyl-5(6,7,8)-nitro-1,2-dihydroquinolin-2-yl)benzamides were synthesized for the first time by the action of amide anions of aromatic acids on the N-methyl salts of 5-, 6-, 7-, and 8-nitroquinolines in anhydrous MeCN. Oxidative dehydrogenation of these amides afforded aroylimino derivatives of the corresponding 1-methyl-5(6,7,8)-nitro-2-quinolones.

Keywords


nitroquinoline N-methyl cations; nitroquinolines; nucleophilic addition.

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