SYNTHESIS OF NOVEL N,O-MACROCYCLIC LIGANDS, FUNCTIONALIZED BY PHOSPHINE OXIDE GROUPS
Authors
Елена А. Александрова
Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
Кристина А. Лоцман
Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
Константин А. Лысенко
зав.кафедрой органической химии Петербургского технологического университета растительных полимеров
A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences,
28 Vavilova St., Moscow 119991, Russia
Юрий Г. Тришин
Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
α-aminophosphoryl compounds, N, O-macrocyclic ligands, Kabachnik–Fields reaction, Pudovik reaction.
Abstract
As a result of the implementation of two approaches, the Pudovik reaction (the reaction of macrocyclic azomethines with secondary phosphine oxides) and the Kabachnik–Fields reaction (three-component one-pot process involving dialdehydes, diamines, and secondary phosphine oxides), novel N,O-containing macrocyclic ligands with phosphine oxide groups were first obtained. The synthesized macrocycles are a kind of α-aminophosphoryl compounds that can be used in the synthesis of supramolecular systems.
Author Biographies
Елена А. Александрова, Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
кафедра органической химии, аспирант
Кристина А. Лоцман, Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
кафедра органической химии, инженер
Константин А. Лысенко, зав.кафедрой органической химии Петербургского технологического университета растительных полимеров
A.N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences,
28 Vavilova St., Moscow 119991, Russia
лаборатория РСА, ведущ. научн. сотр.
Юрий Г. Тришин, Higher School of Technology and Energy,
Saint Petersburg State University of Industrial Technologies and Design, 4 Ivana Chernykh St., Saint Petersburg 198095, Russia
