REACTIONS OF 5-DIAZO-4-NITROIMIDAZOLE WITH HYDROCHLORIC ACID

Authors

  • E. В. Садчикова Urals State Technical University - Urals Polytechnical Institute
  • В. C. Мокрушин Urals State Technical University - Urals Polytechnical Institute
  • T. А. Поспелова Urals State Technical University - Urals Polytechnical Institute
  • И. C. Селезнева Urals State Technical University - Urals Polytechnical Institute

DOI:

https://doi.org/10.1007/529

Abstract

Reaction of 5-diazo-4-nitroimidazole with concentrated hydrochloric acid leads to 4-chloro-5-diazoimidazole. The same product is formed together with a small quantity of 5-chloro-4-nitroimidazole with 1 N hydrochloric acid, but with 0.1 N hydrochloric acid only chloronitroimidazole was isolated. The results obtained are explained with the aid of quantum chemical calculations.

Authors: E. V. Sadchikova, V. S. Mokrushin, T. A. Pospelova, and I. S. Selezneva.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (2), pp 176-179

http://link.springer.com/article/10.1007/BF02251705

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Published

2013-04-26

Issue

No. 2 (1999)

Section

Original Papers