REACTIONS OF 4-METHYL- AND 4,6-DIMETHYLRESORCINOLS WITH (2-ETHOXYVINYL)PHOSPHONIC DICHLORIDE – SYNTHESIS OF NEW REGIOISOMERIC CAGE PHOSPHONATES

Authors

  • Yulia M. Sadykova Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
  • Alena V. Zalaltdinova Kazan National Research Technological University
  • Larisa M. Trofimova Chyvash State University named after I.N. Ulyanov
  • Alexander R. Burilov Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences
  • Mikhail A. Pudovik Arbuzov Institute of Organic and Physical Chemistry, FRC Kazan Scientific Center, Russian Academy of Sciences

DOI:

https://doi.org/10.1007/5315

Keywords:

4, 6-dimethylresorcinol, (2-ethoxyvinyl)phosphonic dichloride, 4-methylresorcinol, cage phosphonates.

Abstract

Regioisomeric cage phosphonates have been prepared and isolated for the first time by the reaction of 4-methyl- and 4,6-dimethylresorcinols with (2-ethoxyvinyl)phosphonic dichloride. It has been shown that different phosphorus-containing heterocyclic compounds are formed depending on the nature of substituent at positions 4 and 6 of resorcinol aromatic ring.

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Published

2019-11-13

Issue

Vol. 55 No. 11 (2019)

Section

Short Communications