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TETRAKIS(HYDROXYMETHYL)GLYCOLURIL IN N-METHYLENATION REACTIONS WITH ARYLAMINES

Светлана Ю. Паньшина, Оксана В. Пономаренко, Абдигали А. Бакибаев, Виктор С. Мальков
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Abstract


This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines, based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyde molecule. It was shown by HPLC that tetrakis-(hydroxymethyl)glycoluril under the studied conditions is subject to dehydroxymethylation processes.

 


Keywords


aminals; arylamines; formaldehyde; tetrakis(hydroxymethyl)glycoluryl; dehydroxymethylation; HPLC.

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