TETRAKIS(HYDROXYMETHYL)GLYCOLURIL IN <i>N</i>-METHYLENATION REACTIONS WITH ARYLAMINES

Authors

  • Светлана Ю. Паньшина National Research Tomsk State University, 36 Lenina Ave., Tomsk 634050, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050, Russia
  • Оксана В. Пономаренко L. N. Gumilyov Eurasian National University, 2 Sambaeva St., Nur-Sultan 010000, Kazakhstan
  • Абдигали А. Бакибаев National Research Tomsk State University, 36 Lenina Ave., Tomsk 634050,
  • Виктор С. Мальков National Research Tomsk State University, 36 Lenina Ave., Tomsk 634050,

DOI:

https://doi.org/10.1007/5451

Keywords:

aminals, arylamines, formaldehyde, tetrakis(hydroxymethyl)glycoluryl, dehydroxymethylation, HPLC.

Abstract

This work shows for the first time the use of tetrakis(hydroxymethyl)glycoluril in the melt N-methylenation reactions of arylamines, based on the ability of tetrakis(hydroxymethyl)glycoluril to eliminate a formaldehyde molecule. It was shown by HPLC that tetrakis-(hydroxymethyl)glycoluril under the studied conditions is subject to dehydroxymethylation processes.

 

Author Biography

Светлана Ю. Паньшина, National Research Tomsk State University, 36 Lenina Ave., Tomsk 634050, National Research Tomsk Polytechnic University, 30 Lenina Ave., Tomsk 634050, Russia

Аспирант химических наук Национального исследовательского Томского политехнического университета. Лаборант лаборатории органического синтеза Национального исследовательского Томского государственного университета.

Downloads

Published

2020-01-31

Issue

Vol. 56 No. 1 (2020)

Section

Short Communications