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N-(ALKOXY)- AND N-(ACYLOXY)PHTHALIMIDES IN ORGANIC SYNTHESIS: FREE RADICAL SYNTHETIC APPROACHES AND APPLICATIONS

Alexander S. Budnikov, Igor B. Krylov
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Abstract


The microreview covers selected examples of the free radical cross-dehydrogenative C–O coupling of various CH reagents with N-hydroxyphthalimide leading to N-(alkoxy)- and N-(acyloxy)phthalimides.
Synthetic applications of the latter associated with the cleavage of N–O bond leading to the O-, N- and C-centered free radicals are also reviewed.

Keywords


N-hydroxypthalimide; cross-dehydrogenative coupling; free radicals; photoredox catalysis

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