SYNTHESIS AND REACTIONS OF CHROMAN-2-OLS AND THEIR BENZO ANALOGS WITH N-NUCLEOPHILES

Authors

  • Ирина А. Семенова Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Кирилл С. Корженко Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Дмитрий В. Осипов Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Виталий А. Осянин Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia
  • Юрий Н. Климочкин Samara State Technical University, 244 Molodogvardeyskaya St., Samara 443100, Russia

DOI:

https://doi.org/10.1007/5498

Keywords:

N, O-acetals, 2-aminochromanes, chroman-2-ols, 2, 3-dihydro-1H-benzo[f]chromen-3-ol, N-nucleophiles.

Abstract

By the action of acetic acid on 2-morpholinochromanes, a series of chroman-2-ols were obtained in which the hydroxyl group is easily substituted by a primary or secondary amine or benzyl carbamate fragments. In the case of hydrazines and hydrazides of carboxylic acids, the corresponding hydrazones are isolated.

Published

2020-04-01

Issue

Section

Original Papers