ELECTROPHILIC REACTIONS OF 5-ARYLTETRAZOLES: SYNTHESIS OF ISOMERIC 2-(ADAMANTAN-1-YL)-5-NITROPHENYL-2Н-TETRAZOLES AND THEIR DERIVATIVES

Abstract

The reaction of isomeric 5-nitrophenyl-NH-tetrazoles with adamantan-1-ol in concentrated sulfuric acid gave rise to new isomeric 2-(adamantan-1-yl)-5-nitrophenyl-2H-tetrazoles, nitration and reduction of which produced the corresponding dinitro and amino derivatives. The structures of the obtained compounds were proved by ¹H, ¹³C NMR spectroscopy and high-resolution mass spectrometry. The thermal stability of the dinitro derivative was studied by the method of synchronous thermal analysis.

Authors: Olga V. Mikolaichuk, Daria V. Spasibenko, Rostislav E. Trifonov*