SYNTHESIS OF UNSYMMETRICAL CAGE PHOSPHONATES FROM HETEROCYCLIC SYSTEMS BASED ON 2<i>H</i>-1,2-BENZOXAPHOSPHININE
Authors
Юлия М. Садыкова
A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences,
8 Akademika Arbuzova St., Kazan 420088, Russia
Алена В. Залалтдинова
Kazan National Research Technological University,
68 Karla Marksa St., Kazan 420015, Russia
Атабек К. Смаилов
Kazan National Research Technological University,
68 Karla Marksa St., Kazan 420015, Russia
Лариса М. Трофимова
Chuvash State University named after I. N. Ulianov ,
19 Moskovskiy Ave., Cheboksary 428015, Russia
Юлия К. Воронина
Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences,
31 Leninsky Ave., Moscow 119991, Russia
Plekhanov Russian University of Economics,
36 Stremyanny Lane, Moscow 117997, Russia
Александр Р. Бурилов
A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences,
8 Akademika Arbuzova St., Kazan 420088, Russia
Михаил А. Пудовик
A. E. Arbuzov Institute of Organic and Physical Chemistry of the Kazan Scientific Center, Russian Academy of Sciences,
8 Akademika Arbuzova St., Kazan 420088, Russia
It was found that the reaction of 2-hydroxy-5,7,8-trimethyl-2H-1,2-benzoxaphosphinine 2-oxide with resorcinol and its derivatives as well as sesamol leads to the formation of phosphaneoflavanones in high yields. The obtained phosphaneoflavanones are precursors in the synthesis of novel unsymmetrical cage phosphonates. The structures of the obtained products were confirmed by IR spectroscopy, 1H, 13C NMR spectroscopy, and X-ray structural analysis.
