SYNTHESIS AND TRANSFORMATIONS OF  N -BUTYL-3(5)-NITRO-1,2,4-TRIAZOLES UNDER THE CONDITIONS OF ACID-CATALYZED ALKYLATION OF 3(5)-NITRO-1 H -1,2,4-TRIAZOLES WITH BUTYL ALCOHOLS

Геннадий Т. Суханов; Ирина А. Крупнова; Юлия В. Филиппова; Юрий В. Гатилов; Анна Г. Суханова; Константин К. Босов; Екатерина В. Пивоварова

doi:10.1007/5980

SYNTHESIS AND TRANSFORMATIONS OF N-BUTYL-3(5)-NITRO-1,2,4-TRIAZOLES UNDER THE CONDITIONS OF ACID-CATALYZED ALKYLATION OF 3(5)-NITRO-1H-1,2,4-TRIAZOLES WITH BUTYL ALCOHOLS

Геннадий Т. Суханов, Ирина А. Крупнова, Юлия В. Филиппова, Юрий В. Гатилов, Анна Г. Суханова, Константин К. Босов, Екатерина В. Пивоварова

Abstract

The directions of thermodynamically controlled rearrangements and transformations of alkyl substituents under the conditions of acidcatalyzed
alkylation of unsubstituted and 5(3)-substituted 3(5)-nitro-1H-1,2,4-triazoles with butyl alcohols (n-, i-, tert-, sec-BuOH) were studied.

Keywords

1-(tert-butyl)-4-(sec-butyl)-3-nitro-1,2,4-triazolium salt; 1-(sec-butyl)-3,5-dinitro-1H-1,2,4-triazole; N-(sec-butyl)-3(5)-nitro-1,2,4-triazole; alkylation; isomers; transformation of alkyl substituent; X-ray structural analysis.

Full Text: PDF (Russian) Open Access

Supplementary File(s): None

Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv

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