The possibility of constructing various N-, S-, O-containing heterocyclic systems based on the transformations of 1-((Z)-1,4-dibromobut-2-en-2-yl)adamantane was shown. Adamantyl-containing pyrrolines, pyrroles, pyridazinium salt, furan, thiophene, (dihydro)-1,6-benzodioxocine, diazocine, oxazocine, thiazocine were synthesized. It was found that the dihydro derivatives formed as a result of the reactions are unstable and can be easily oxidized by atmospheric oxygen to the corresponding heteroaromatic compounds.
Author Biographies
Марат Р. Баймуратов, Samara State Technical University,
244 Molodogvardeyskaya St., Samara 443100, Russia
Кафедра органической химии, к.х.н., доцент
Марина В. Леонова, Samara State Technical University,
244 Molodogvardeyskaya St., Samara 443100, Russia
Кафедра органической химии, к.х.н., доцент
Юрий Н. Климочкин, Samara State Technical University,
244 Molodogvardeyskaya St., Samara 443100, Russia
Кафедра органической химии, д.х.н., профессор, заведующий кафедрой
