NEW HETEROBIMETALLIC RUTHENIUM(II) COMPLEX WITH IMIDAZO[4,5-<i>f</i>][1,10]PHENANTHROLINE-BASED LIGAND: SYNTHESIS, OPTICAL AND ELECTROCHEMICAL PROPERTIES

Authors

  • Sergey D. Tokarev A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991
  • Anatoly Botezatu A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991
  • Yuri V. Fedorov A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991
  • Olga A. Fedorova A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 Vavilova St., Moscow 119991

DOI:

https://doi.org/10.1007/6263

Keywords:

imidazo[4, 5-f][1, 10]phenanthroline, ruthenium complex, bimetallic complex, cyclic voltammetry, luminescence

Abstract

Ditopic ligand with coordination centers of different types was synthesized. Ligand contains 1,10-phenanthroline fragment for Ru(II) coordination and azadithiacrown ether moiety for Cu(II) cation binding. At first step, new ruthenium complex was synthesized and then its complexation with Cu(II) perchlorate was studied by optical and electrochemical means. The complex obtained in this work represents a rare type of bimetallic complexes, in which both cations are located in one ligand system, but their effect on each other is measurable.

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Published

2021-08-26

Issue

Vol. 57 No. 7/8 (2021)

Section

Original Papers