

N-3,3,3-TRIFLUOROPROPENYL DERIVATIVES OF AZOLES

Abstract
The reaction of trans-1-chloro-3,3,3-trifluoropropene with nitrogenous heterocycles was studied, the relationships between the nature of the heterocycle, the reaction temperature, and the ratio of cis- and trans-isomers in the final substitution products were considered. Azoles containing a trans-3,3,3-trifluoropropenyl group at the nitrogen atom were isolated.
Authors: Kirill I. Petko*, Andrey А. Filatov, Yurii L. Yagupolskii
Keywords
imidazoles; pyrazoles; trans-1-chloro-3,3,3-trifluoropropene; triazoles; cis-trans isomerism
Latvian Institute of Organic Synthesis - Aizkraukles iela, 21, Riga, LV-1006, Latvia - hgs@osi.lv