FREE RADICALS FROM ELECTROCHEMICAL REDUCTION OF HEXAHYDROQUINOLONES AND HEXAHYDROISOQUINOLONES

Authors

  • P. Гаварс Латвийский институт органического синтеза
  • Л. Баумане Latvian Institute of Organic Synthesis
  • Я. Страдынь Latvian Institute of Organic Synthesis
  • Б. Виганте Latvian Institute of Organic Synthesis
  • Я. Озолс Latvian Institute of Organic Synthesis
  • Г. Дубурс Latvian Institute of Organic Synthesis

DOI:

https://doi.org/10.1007/688

Abstract

Electrochemical reduction of 3,5-diethoxycarbonyl- and 3,5-diacetyl-2,6-dimethyl-1,4-dihydropyrdine, hexahydroquinol-5-one, and hexahydroisoquinol-8-one, which contain dihydropyridine moieties, produces free radicals detectable by EPR only for the most easily reduced hexahydroisoquinol-8-ones. The hyperfine structure of the EPR spectra is determined and is consistent with that for the 4,5-dihydropyridine moiety.

Authors: R. Gavars, L. Baumane, J. Stradins, B. Vigante, J. Ozols, and G. Duburs.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (7), pp 809-812

http://link.springer.com/article/10.1007/BF02252105

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Published

2013-06-06

Issue

No. 7 (1999)

Section

Original Papers