SYNTHESIS AND STRUCTURE OF 3-SUBSTITUTED 1,5-DINITRO-1,3,5-TRIAZEPANES

Authors

  • Павел С. Грибов N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Дмитрий Ф. Франк N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991 D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047
  • Анфиса Д. Гетманова N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991 D. Mendeleev University of Chemical Technology of Russia, 9 Miusskaya Sq., Moscow 125047
  • Кирилл Ю. Супоницкий N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991
  • Алексей Б. Шереметев N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

DOI:

https://doi.org/10.1007/6889

Keywords:

nitroamines, 1, 3, 5-triazepanes, four-component Mannich reaction, NMR, X-ray structural analysis

Abstract

A method has been optimized for the condensation of ethylenedinitroamine with aliphatic amines and formalaldehyde, leading to the formation of 3-alkyl-1,5-dinitro-1,3,5-triazepanes. The structure of the obtained 1,3,5-triazepanes was studied by multinuclear NMR and X-ray structural analysis.

Authors: Pavel S. Gribov, Dmitry F. Frank, Anfisa D. Getmanova, Kyrill Yu. Suponitsky, Aleksei B. Sheremetev*

Author Biography

Павел С. Грибов, N. D. Zelinsky Institute of Organic Chemistry, Russian Academy of Sciences, 47 Leninsky Ave., Moscow 119991

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Published

2022-10-20

Issue

Vol. 58 No. 10 (2022): Chemistry of polyheteroatomic heterocyclic systems

Section

Original Papers