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SYNTHESIS AND STRUCTURE OF 3-SUBSTITUTED 1,5-DINITRO-1,3,5-TRIAZEPANES

Павел С. Грибов, Дмитрий Ф. Франк, Анфиса Д. Гетманова, Кирилл Ю. Супоницкий, Алексей Б. Шереметев
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Abstract


A method has been optimized for the condensation of ethylenedinitroamine with aliphatic amines and formalaldehyde, leading to the formation of 3-alkyl-1,5-dinitro-1,3,5-triazepanes. The structure of the obtained 1,3,5-triazepanes was studied by multinuclear NMR and X-ray structural analysis.

Authors: Pavel S. Gribov, Dmitry F. Frank, Anfisa D. Getmanova, Kyrill Yu. Suponitsky, Aleksei B. Sheremetev*


Keywords


nitroamines; 1,3,5-triazepanes; four-component Mannich reaction; NMR; X-ray structural analysis

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