SYNTHESIS, STRUCTURE, SPECTRAL, AND ELECTROCHEMICAL PROPERTIES OF THE Au(I) COMPLEX WITH 5-METHOXY-8-(N-PICRYLAMINO)QUINOLINE

Authors

  • К. И. Грaндбeрг M. V. Lomonosov Moscow State University
  • Л. Г. Кузьмина M. V. Lomonosov Moscow State University
  • Г. Г. Александров M. V. Lomonosov Moscow State University
  • И. Г. Ильина M. V. Lomonosov Moscow State University
  • O. В. Михалев M. V. Lomonosov Moscow State University
  • Р. Д. Рахимов M. V. Lomonosov Moscow State University
  • К. П. Бутин M. V. Lomonosov Moscow State University

DOI:

https://doi.org/10.1007/725

Abstract

The synthesis of a gold(I) chelate complex obtained from an autocomplex of the picryl series with a quinoline-containing donor fragment is described. The crystal structure was established by X-ray analysis, the spectral and electrochemical properties were studied. The molecules of the complex obtained have a conformation in which both o-NO2 groups of the picryl fragment participate in intramolecular charge transfer by contact.

Authors: K. I. Grandberg, L. G. Kuz'mina, G. G. Aleksandrov, I. G. Il'ina, O. V. Mikhalev, R. D. Rakhimov, and K. P. Butin.

English Translation in Chemistry of Heterocyclic Compounds, 1999, 35 (8), pp 900-906

http://link.springer.com/article/10.1007/BF02252157

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Published

2013-06-18

Issue

No. 8 (1999)

Section

Original Papers